Browsing by Subject "Gas phase."
Now showing items 1-2 of 2
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Construction and calibration of a custom time-of-flight mass spectrometer and its use in measuring the reaction kinetics of transition metal ion-organic interactions.
(2009-09-03)A unique instrument was constructed and used to generate and interrogate jet cooled neutrals, ions and their respective clusters. The instrument is a result of the artful marriage of supersonic expansions combined with ... -
Metal ion assisted unimolecular decomposition of gaseous organometallic complexes : acquisition of reaction rate constants and dynamics of the dissociative mechanism.
(, 2011-12-19)Reaction rate constants have been acquired for the transition metal ion assisted decomposition of various organic molecules, and their deuterium labeled analogs in the gas phase. The metal ion activates organic bonds and ...