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Luminescent supramolecular silver(I) coordination complexes of pyridyl-substituted phosphinites, phosphonites and amines.
Interest in the design and synthesis of supramolecular metal-organic coordination polymers has increased exponentially in the last decade. This attraction comes along with advances in crystallographic instrumentation that ...
Chemistry, electrochemistry and electron transfer induced reactions of cobalt complexes with fluorinated ligands.
The chemical or electrochemical reduction of the trifluoroacetyl complex CF3COCo(CO)3PPh3 involves a single electron transfer yielding trifluoromethyl radical and an anionic cobalt carbonyl complex. The mechanism is ...
Synthesis and characterization of silver(I) salts with amino methyl pyridines containing phosphines: novel complex formation upon ratio, anion, or ligand changes.
Phosphorus ligands are well recognized for stabilizing metal complexes in a variety of oxidation states and coordination geometries.1 Compounds with pyridyl containing phosphines have been investigated with carbinol groups ...