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Synthesis and application of C₂ asymmetric phosphinines via their pyrylium salt precursors.
The development of new chiral ligands for asymmetric catalysis is an increasingly important area of research. Though many ligands are phosphorus based, one class of phosphorus ligands, phosphinines (phosphabenzenes), have ...
Discovery of DNA-enzymes dependent on small-molecule cofactors; design, synthesis and evaluation of TLR-7 agonists and their immunoprotein conjugates.
Several catalytic families of DNA enzymes (deoxyribozymes) have previously been isolated through the use of an in vitro selection technique in our laboratory. The activities of these deoxyribozymes appear to be dependent ...