Synthesis and characterization of silver(I) salts with amino methyl pyridines containing phosphines: novel complex formation upon ratio, anion, or ligand changes.

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dc.contributor.advisorKlausmeyer, Kevin Kenneth, 1969-
dc.contributor.authorAmawi, Rema Mouawya.
dc.contributor.departmentChemistry and Biochemistry.en
dc.contributor.otherBaylor University. Dept. of Chemistry and Biochemistry.en
dc.date.accessioned2008-06-10T21:57:15Z
dc.date.available2008-06-10T21:57:15Z
dc.date.copyright2008-05
dc.date.issued2008-06-10T21:57:15Z
dc.descriptionIncludes bibliographical references (p. 116-119).en
dc.description.abstractPhosphorus ligands are well recognized for stabilizing metal complexes in a variety of oxidation states and coordination geometries.1 Compounds with pyridyl containing phosphines have been investigated with carbinol groups in the past; this work studies the pyridyl amines. The focus of this research is to explore the different binding properties as the position of the nitrogen changes on the ligand, as well as changing the silver(I) salts binding to the ligand such as the BF₄⁻ , OTf⁻ and the tfa⁻ anions. The synthesis and characterization of two new ligands that are from the same family have been looked at, and the synthesis of novel silver(I) complexes involving these ligands have been explored. All of the compounds produced have been characterized by X-ray crystallography, NMR spectroscopy, fluorescence, and elemental analyses.en
dc.description.degreeM.S.en
dc.description.statementofresponsibilityby Rema Mouawya Amawi.en
dc.format.extentxv, 119 p. : ill.en
dc.format.extent3514762 bytes
dc.format.extent139005 bytes
dc.format.mimetypeapplication/pdf
dc.format.mimetypeapplication/pdf
dc.identifier.urihttp://hdl.handle.net/2104/5180
dc.language.isoen_USen
dc.rightsBaylor University theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. Contact librarywebmaster@baylor.edu for inquiries about permission.en
dc.rights.accessrightsBaylor University access onlyen
dc.subjectCoordination compounds -- Synthesis.en
dc.subjectLigands.en
dc.subjectAmines.en
dc.subjectSilver salts.en
dc.subjectPyridine.en
dc.subjectPhosphine.en
dc.titleSynthesis and characterization of silver(I) salts with amino methyl pyridines containing phosphines: novel complex formation upon ratio, anion, or ligand changes.en
dc.typeThesisen

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