Generating conjugated boron heterocycles from Boroles.

Yruegas, Samantha, 1992-

Generating conjugated boron heterocycles from Boroles.

dc.contributor.advisor	Martin, Caleb D.
dc.creator	Yruegas, Samantha, 1992-
dc.date.accessioned	2019-12-04T15:47:35Z
dc.date.available	2019-12-04T15:47:35Z
dc.date.created	2019-08
dc.date.issued	2019-06-04
dc.date.submitted	August 2019
dc.date.updated	2019-12-04T15:47:35Z
dc.description.abstract	Much of the existing methodology for the construction of cyclic systems does not translate for boron-containing rings. With both limited routes and the restricted amount of commercially available reagents, significant progress is necessary to expand the library of known boracycles. Boroles, highly reactive four π-electron heterocycles, are a family of compounds with the potential to serve to as effective reagents to produce boron heterocycles with extended conjugation. The current work capitalizes on this ring expansion methodology to access six- and seven-membered heterocycles via 1,1- and 1,2-insertion reactions, respectively. These findings demonstrate that boroles, and their benzofused relatives 9-borafluorenes, are synthons for the construction of unique boracyclic architectures.
dc.format.mimetype	application/pdf
dc.identifier.uri	https://hdl.handle.net/2104/10762
dc.language.iso	en
dc.rights.accessrights	Worldwide access
dc.subject	Boron heterocycles. Boroles. Borafluorene.
dc.title	Generating conjugated boron heterocycles from Boroles.
dc.type	Thesis
dc.type.material	text
thesis.degree.department	Baylor University. Dept. of Chemistry & Biochemistry.
thesis.degree.grantor	Baylor University
thesis.degree.level	Doctoral
thesis.degree.name	Ph.D.